Optical limiting in modified meso-alkynyl porphyrins

被引:9
作者
Tang, NS [1 ]
Su, WJ [1 ]
Krein, DM [1 ]
McLean, DG [1 ]
Brant, MC [1 ]
Fleitz, PA [1 ]
Brandelik, DM [1 ]
Sutherland, RL [1 ]
Cooper, TM [1 ]
机构
[1] USAF, Wright Lab, MLPJ, Mat Directorate, Wright Patterson AFB, OH 45433 USA
来源
MATERIALS FOR OPTICAL LIMITING II | 1997年 / 479卷
关键词
D O I
10.1557/PROC-479-47
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We characterize the optical properties of modified meso-alkynyl porphyrins by a number of techniques. Our data show that extending the conjugation and incorporating metal in the center of the ring in these molecules serve the objective of tuning the absorption maximum wavelength. We evaluate the optical limiting performance by determining the effective reverse-saturable-absorption (RSA) lifetime and the change in the absorption cross-sections. The ultimate optical limiting performance of these molecules is tested in both picosecond and nanosecond regimes.
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页码:47 / 52
页数:6
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