Effect of preparation conditions on the catalytic performance of copper manganese oxide catalysts for CO oxidation

被引：176

作者：

Hutchings, GJ

Mirzaei, AA

Joyner, RW

Siddiqui, MRH

Taylor, SH

机构：

[1] Univ Liverpool, Dept Chem, Leverhulme Ctr Innovat Catalysis, Liverpool L69 3BX, Merseyside, England

[2] Nottingham Trent Univ, Dept Chem, Ctr Catalysis Res, Nottingham NG11 8NS, England

来源：

APPLIED CATALYSIS A-GENERAL | 1998年 / 166卷 / 01期

关键词：

copper manganese oxide catalyst; preparation condition; CO oxidation;

D O I：

10.1016/S0926-860X(97)00248-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Copper manganese oxides are prepared using a coprecipitation procedure and studied for the oxidation of CO at ambient temperature. In particular, the effect of a range of preparation variables are investigated in detail. The variables investigated include the precipitate ageing time, pH and temperature of precipitation: the [Cu]/[Mn] ratio of the precipitation solution and the catalyst calcination temperature. The optimum preparation conditions are identified with respect to the catalyst activity for the oxidation of CO at ambient temperature. The results are interpreted in terms of the structure of the active catalyst. Generally it has been concluded that catalysts containing copper/manganese mixed phases are found to be the most active. (C) 1998 Elsevier Science B.V.

引用

页码：143 / 152

页数：10

共 11 条

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