Dielectric response of aligned semiconducting single-wall nanotubes

被引:76
作者
Fagan, J. A. [1 ]
Simpson, J. R.
Landi, B. J.
Richter, L. J.
Mandelbaum, I.
Bajpai, V.
Ho, D. L.
Raffaelle, R.
Walker, A. R. Hight
Bauer, B. J.
Hobbie, E. K.
机构
[1] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA
[2] Rochester Inst Technol, Nanopower Res Labs, Rochester, NY 14623 USA
关键词
D O I
10.1103/PhysRevLett.98.147402
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We report measurements of the full intrinsic optical anisotropy of isolated single-wall carbon nanotubes (SWNTs). By combining absorption spectroscopy with transmission ellipsometry and polarization-dependent resonant Raman scattering, we obtain the real and imaginary parts of the SWNT permittivity from aligned semiconducting SWNTs dispersed in stretched polymer films. Our results are in agreement with theoretical predictions, highlighting the limited polarizability of excitons in a quasi-1D system.
引用
收藏
页数:4
相关论文
共 37 条
[1]   Small-angle neutron scattering from labeled single-wall carbon nanotubes [J].
Bauer, BJ ;
Hobbie, EK ;
Becker, ML .
MACROMOLECULES, 2006, 39 (07) :2637-2642
[2]   Carbon nanotubes - the route toward applications [J].
Baughman, RH ;
Zakhidov, AA ;
de Heer, WA .
SCIENCE, 2002, 297 (5582) :787-792
[3]   STATIC POLARIZABILITIES OF SINGLE-WALL CARBON NANOTUBES [J].
BENEDICT, LX ;
LOUIE, SG ;
COHEN, ML .
PHYSICAL REVIEW B, 1995, 52 (11) :8541-8549
[4]   ALIGNED CARBON NANOTUBE FILMS - PRODUCTION AND OPTICAL AND ELECTRONIC-PROPERTIES [J].
DEHEER, WA ;
BACSA, WS ;
CHATELAIN, A ;
GERFIN, T ;
HUMPHREYBAKER, R ;
FORRO, L ;
UGARTE, D .
SCIENCE, 1995, 268 (5212) :845-847
[5]   Polarized Raman spectroscopy on isolated single-wall carbon nanotubes [J].
Duesberg, GS ;
Loa, I ;
Burghard, M ;
Syassen, K ;
Roth, S .
PHYSICAL REVIEW LETTERS, 2000, 85 (25) :5436-5439
[6]   Structural dependence of excitonic optical transitions and band-gap energies in carbon nanotubes [J].
Dukovic, G ;
Wang, F ;
Song, DH ;
Sfeir, MY ;
Heinz, TF ;
Brus, LE .
NANO LETTERS, 2005, 5 (11) :2314-2318
[7]  
Edwards D.F., 1985, Handbook of optical constants of solids
[8]   Comparative measures of single-wall carbon nanotube dispersion [J].
Fagan, J. A. ;
Landi, B. J. ;
Mandelbaum, I. ;
Simpson, J. R. ;
Bajpai, V. ;
Bauer, B. J. ;
Migler, K. ;
Walker, A. R. Hight ;
Raffaelle, R. ;
Hobbie, E. K. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (47) :23801-23805
[9]   Anisotropy of sheared carbon-nanotube suspensions [J].
Fry, D ;
Langhorst, B ;
Kim, H ;
Grulke, E ;
Wang, H ;
Hobbie, EK .
PHYSICAL REVIEW LETTERS, 2005, 95 (03)
[10]   Linear and nonlinear optical properties of carbon nanotubes from first-principles calculations [J].
Guo, GY ;
Chu, KC ;
Wang, DS ;
Duan, CG .
PHYSICAL REVIEW B, 2004, 69 (20) :205416-1