Composition and stability of decagonal quasicrystals in the Zn-Mg-rare-earth systems

被引:44
作者
Sato, TJ [1 ]
Abe, E [1 ]
Tsai, AP [1 ]
机构
[1] Natl Res Inst Met, Tsukuba, Ibaraki 305, Japan
关键词
D O I
10.1080/095008398178534
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Decagonal quasicrystals in Zn-Mg-RE systems (RE = rare earth) have been studied for their composition and stability. The decagonal phase was shown to have the composition Zn58Mg40Dy2 in the Zn-Mg-Dy system. This phase became a major phase after annealing and thus is apparently thermodynamically stable. Further, the decagonal phase was observed for RE = Y, Dy, Ho, Er, Tm and Lu. All these RE elements have Goldschmidt atomic diameters smaller than 3.55 Angstrom, suggesting that the atomic diameter is an intrinsic parameter in stabilizing the decagonal phase.
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页码:213 / 219
页数:7
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