Novel double insertion of carbon disulfide into two Ru-H bonds of [(dppm)2Ru(H)2] (dppm = Ph2PCH2PPh2):: Synthesis and crystal structure of a methanedithiolate complex

被引：21

作者：

Gandhi, T ^{[1
]}

Nethaji, M ^{[1
]}

Jagirdar, BR ^{[1
]}

机构：

[1] Indian Inst Sci, Dept Inorgan & Phys Chem, Bangalore 560012, Karnataka, India

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 03期

关键词：

D O I：

10.1021/ic0260320

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Addition of excess carbon disulfide to cis/trans-[(dPPM)(2)Ru(H)(2)] results in the methanedithiolate complex [(dppm)(2)Ru(eta(2)-S2CH2)] 4 via the intermediacy of cis-[(dppm)(2)Ru(H)(SC(S)H)] 2. The X-ray crystal structure of this species has been determined.

引用

页码：667 / 669

页数：3

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