Cycle life modeling of lithium-ion batteries

被引：342

作者：

Ning, G ^{[1
]}

Popov, BN ^{[1
]}

机构：

[1] Univ S Carolina, Dept Chem Engn, Columbia, SC 29208 USA

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2004年 / 151卷 / 10期

关键词：

D O I：

10.1149/1.1787631

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A first-principles-based charge-discharge model was developed to simulate the capacity fade of Li-ion batteries. The model is based on the loss of active lithium ions due to solvent reduction reaction and on the rise of the anode film resistance. The effect of parameters such as exchange current density, depth of discharge (DOD), end of charge voltage, film resistance, and the overvoltage of parasitic reaction were studied quantitatively. The model controls the required DOD by controlling the discharge time and estimates the end of discharge voltages as a function of cycle number. (C) 2004 The Electrochemical Society.

引用

页码：A1584 / A1591

页数：8

共 16 条

[1] Review of selected electrode-solution interactions which determine the performance of Li and Li ion batteries [J].

Aurbach, D .

JOURNAL OF POWER SOURCES, 2000, 89 (02) :206-218

[2] A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions [J].

Aurbach, D ;

Zinigrad, E ;

Cohen, Y ;

Teller, H .

SOLID STATE IONICS, 2002, 148 (3-4) :405-416

[3] Recent studies on the correlation between surface chemistry, morphology, three-dimensional structures and performance of Li and Li-C intercalation anodes in several important electrolyte systems [J].

Aurbach, D ;

Zaban, A ;

Ein-Eli, Y ;

Weissman, I ;

Chusid, O ;

Markovsky, B ;

Levi, M ;

Levi, E ;

Schechter, A ;

Granot, E .

JOURNAL OF POWER SOURCES, 1997, 68 (01) :91-98

[4] An accelerated calendar and cycle life study of Li-ion cells [J].

Bloom, I ;

Cole, BW ;

Sohn, JJ ;

Jones, SA ;

Polzin, EG ;

Battaglia, VS ;

Henriksen, GL ;

Motloch, C ;

Richardson, R ;

Unkelhaeuser, T ;

Ingersoll, D ;

Case, HL .

JOURNAL OF POWER SOURCES, 2001, 101 (02) :238-247

[5] Aging mechanism in Li ion cells and calendar life predictions [J].

Broussely, M ;

Herreyre, S ;

Biensan, P ;

Kasztejna, P ;

Nechev, K ;

Staniewicz, RJ .

JOURNAL OF POWER SOURCES, 2001, 97-8 :13-21

[6] Effect of anode film resistance on the charge/discharge capacity of a lithium-ion battery [J].

Christensen, J ;

Newman, J .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (11) :A1416-A1420

[7] Modeling side reactions in composite LiyMn2O4 electrodes [J].

Darling, R ;

Newman, J .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (03) :990-998

[8] MODELING OF GALVANOSTATIC CHARGE AND DISCHARGE OF THE LITHIUM POLYMER INSERTION CELL [J].

DOYLE, M ;

FULLER, TF ;

NEWMAN, J .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (06) :1526-1533

[9]

INOUE T, 2001, NASA AER BATT WORKSH

[10] Capacity fade study of lithium-ion batteries cycled at high discharge rates [J].

Ning, G ;

Haran, B ;

Popov, BN .

JOURNAL OF POWER SOURCES, 2003, 117 (1-2) :160-169

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