Characterization of "spectroscopically quiet" metals in biology

被引：133

作者：

Penner-Hahn, JE ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Div Biophys Res, Ann Arbor, MI 48109 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2005年 / 249卷 / 1-2期

基金：

美国国家卫生研究院;

关键词：

spectroscopically quiet; X-ray absorption; Cu(I); Zn(II); EXAFS; XANES; XAS;

D O I：

10.1016/j.ccr.2004.03.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The use of X-ray absorption spectroscopy (XAS) to characterize the local environment of "spectroscopically quiet" metals in metalloproteins is reviewed, with an emphasis on studies of Cu(I) and Zn(II). Both the advantages and the weaknesses of X-ray absorption are discussed, with examples taken from the recent literature. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：161 / 177

页数：17

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