Universal coulometric nanotitrators with potentiometric detection

被引：29

作者：

Guenat, OT ^{[1
]}

Morf, WE ^{[1
]}

van der Schoot, BH ^{[1
]}

de Rooij, NF ^{[1
]}

机构：

[1] Univ Neuchatel, Inst Microtechnol, CH-2007 Neuchatel, Switzerland

来源：

ANALYTICA CHIMICA ACTA | 1998年 / 361卷 / 03期

关键词：

nanotitration; coulometry; potentiometric detection;

D O I：

10.1016/S0003-2670(98)00034-8

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

This paper reports and fully characterizes a coulometric nanotitrator and its application for four different types of titrations: precipitation, complex-formation. redox and acid-base nanotitrations. This simple device, composed of Pt or Ag planar electrodes located in a microchannel, gives very reproducible results and yields a linear relationship between the analyte concentration and the equivalence time for concentrations up to 10(-2) M of analyte. (C) 1998 Elsevier Science B.V.

引用

页码：261 / 272

页数：12

共 15 条

[1] Development of a sequential microtitration system [J].

Alerm, L ;

Bartroli, J .

ANALYTICAL CHEMISTRY, 1996, 68 (08) :1394-1400

[2]

BARD AJ, 1980, ELECTROCHEMICAL METH

[3]

GRETILLAT MA, 1996, P EUROSENSORS, V10, P259

[4]

GUENAT OT, 1998, P 1 INT C MICR TECHN, P340

[5]

GUENAT OT, 1997, P TRANSD 97 CHIC US, P1375

[6]

GUENAT OT, 1996, P 2 INT S MIN TOT AN, P215

[7] A new titration method: Electrodeposition frequency shift titrimetry [J].

He, FJ ;

Shi, JJ ;

Xie, QG ;

Nie, LH ;

Yao, SZ .

MICROCHEMICAL JOURNAL, 1995, 52 (03) :325-332

[8]

LINGANE JJ, 1958, ELECTROANALYTICAL CH, P129

[9] MODELING OF COULOMETRIC SENSOR ACTUATOR SYSTEMS BASED ON ISFETS WITH A POROUS ACTUATOR COVERING THE GATE [J].

LUO, J ;

OLTHUIS, W ;

BERGVELD, P ;

BOS, M ;

VANDERLINDEN, WE .

ANALYTICA CHIMICA ACTA, 1993, 274 (01) :7-23

[10] PREPARATION OF IRIDIUM OXIDE AND ITS APPLICATION IN SENSOR ACTUATOR SYSTEMS [J].

OLTHUIS, W ;

VANKERKHOF, JC ;

BERGVELD, P ;

BOS, M ;

VANDERLINDEN, WE .

SENSORS AND ACTUATORS B-CHEMICAL, 1991, 4 (1-2) :151-156

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