8-Hydroxyflavonoid glucuronides of Malope trifida

被引:13
作者
Sikorska, M
Matlawska, I
Franski, R
机构
[1] Poznan Univ Med Sci, Dept Pharmacognosy, PL-61771 Poznan, Poland
[2] Adam Mickiewicz Univ, Fac Chem, PL-60780 Poznan, Poland
关键词
Malope trifida; Malvaceae; flavonoids; herbacetin; 3-O-beta-glucopyranoside-8-O-beta-glucuronopyranoside; gossypetin; isoscutellarein derivatives;
D O I
10.1007/s11738-004-0019-6
中图分类号
Q94 [植物学];
学科分类号
071001 [植物学];
摘要
The new flavonoid: herbacetin 3-O-beta-glueopyranoside- 8-O-beta-glucuronopyranoside (1) to-ether with known gossypetin 3-O-beta-glucopyranoside - 8-O-beta-glucuronopyranoside (2) and isoscutellarein: 8-O-beta-glucuronopyranoside (3) as well as 4'-methyl ether-8-O-beta-glucuronopyranoside (4), were isolated from the calyx and epicalyx leaves of Malope trifida and identified on the basis of their spectroscopic properties: UV, H-1 and C-13 NMR, ESUMS. Two other flavonoids were identified as isoscutellarein: 3'-hydroxy 4'-methyl ether-8-O-beta-glucuronoside (5) and 8-O-rhamnoglucoside (6) on the basis of their UV and ESI/MS data.
引用
收藏
页码:291 / 297
页数:7
相关论文
共 19 条
[1]
8-HYDROXYFLAVONOID GLUCURONIDES FROM MALVA-SYLVESTRIS [J].
BILLETER, M ;
MEIER, B ;
STICHER, O .
PHYTOCHEMISTRY, 1991, 30 (03) :987-990
[2]
Differentiation of interglycosidic linkages in permethylated flavonoid glycosides from linked-scan mass spectra (B/E) [J].
Franski, R ;
Matlawska, I ;
Bylka, W ;
Sikorska, M ;
Fiedorow, P ;
Stobiecki, M .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2002, 50 (05) :976-982
[3]
Electrospray mass spectrometric decomposition of some glucuronic acid-containing flavonoid diglycosides [J].
Franski, R ;
Eitner, K ;
Sikorska, M ;
Matlawska, I ;
Stobiecki, M .
PHYTOCHEMICAL ANALYSIS, 2003, 14 (03) :170-175
[4]
[5]
Gudej J., 1987, ACTA POL PHARM, V44, P369
[6]
Gudej J, 1988, ACTA POL PHARM, V45, P340
[7]
HARBONE JB, 1989, METHODS PLANT BIOCH, P201
[8]
GOSSYPETIN AND HERBACETIN AS TAXONOMIC MARKERS IN HIGHER PLANTS [J].
HARBORNE, JB .
PHYTOCHEMISTRY, 1969, 8 (01) :177-&
[9]
HARBORNE JB, 1988, FLAVONOIDS ADV RES 1, P261
[10]
HEGNAUER R, 1960, CHEMOTAXONOMIE PFLAN, V5, P29