A Nanosheets-on-Channel Architecture Constructed from MoS2 and CMK-3 for High-Capacity and Long-Cycle-Life Lithium Storage

被引:163
作者
Xu, Xin [1 ]
Fan, Zhaoyang [1 ]
Yu, Xinyao [2 ]
Ding, Shujiang [1 ]
Yu, Demei [1 ]
Lou, Xiong Wen [2 ]
机构
[1] Xi An Jiao Tong Univ, Dept Appl Chem, MOE Key Lab Nonequilibrium Synth & Modulat Conden, Sch Sci,State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
[2] Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637459, Singapore
基金
中国国家自然科学基金;
关键词
HIGH-PERFORMANCE ANODE; ION BATTERIES; HOLLOW MICROSPHERES; FACILE SYNTHESIS; CNT BACKBONE; CARBON; CATHODE; NANOCOMPOSITES; NANOSPHERES; CHALLENGES;
D O I
10.1002/aenm.201400902
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A unique hybrid nanostructure of ultrathin MoS2 nanosheets on CMK-3 is designed and fabricated as an anode material for lithium-ion batteries. With advantages of the nanosheets-on-channel architecture, the MoS2@CMK-3 electrode is able to deliver a high discharge capacity of 934 mAh g-1 even after 150 cycles at a current density of 400 mA g-1. © 2014 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页数:5
相关论文
共 39 条
[1]   Building better batteries [J].
Armand, M. ;
Tarascon, J. -M. .
NATURE, 2008, 451 (7179) :652-657
[2]   MoS2-MWCNT hybrids as a superior anode in lithium-ion batteries [J].
Bindumadhavan, Kartick ;
Srivastava, Suneel Kumar ;
Mahanty, Sourindra .
CHEMICAL COMMUNICATIONS, 2013, 49 (18) :1823-1825
[3]   Nanomaterials for rechargeable lithium batteries [J].
Bruce, Peter G. ;
Scrosati, Bruno ;
Tarascon, Jean-Marie .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) :2930-2946
[4]   Cu-Si Nanocable Arrays as High-Rate Anode Materials for Lithium-Ion Batteries [J].
Cao, Fei-Fei ;
Deng, Jun-Wen ;
Xin, Sen ;
Ji, Heng-Xing ;
Schmidt, Oliver G. ;
Wan, Li-Jun ;
Guo, Yu-Guo .
ADVANCED MATERIALS, 2011, 23 (38) :4415-+
[5]   L-Cysteine-Assisted Synthesis of Layered MoS2/Graphene Composites with Excellent Electrochemical Performances for Lithium Ion Batteries [J].
Chang, Kun ;
Chen, Weixiang .
ACS NANO, 2011, 5 (06) :4720-4728
[6]   In situ synthesis of MoS2/graphene nanosheet composites with extraordinarily high electrochemical performance for lithium ion batteries [J].
Chang, Kun ;
Chen, Weixiang .
CHEMICAL COMMUNICATIONS, 2011, 47 (14) :4252-4254
[7]   Facile synthesis of hierarchical MoS2 microspheres composed of few-layered nanosheets and their lithium storage properties [J].
Ding, Shujiang ;
Zhang, Dongyang ;
Chen, Jun Song ;
Lou, Xiong Wen .
NANOSCALE, 2012, 4 (01) :95-98
[8]   Glucose-Assisted Growth of MoS2 Nanosheets on CNT Backbone for Improved Lithium Storage Properties [J].
Ding, Shujiang ;
Chen, Jun Song ;
Lou, Xiong Wen .
CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (47) :13142-13145
[9]   Instant gelation synthesis of 3D porous MoS2@C nanocomposites for lithium ion batteries [J].
Fei, Ling ;
Xu, Yun ;
Wu, Xiaofei ;
Chen, Gen ;
Li, Yuling ;
Li, Binsong ;
Deng, Shuguang ;
Smirnov, Sergei ;
Fan, Hongyou ;
Luo, Hongmei .
NANOSCALE, 2014, 6 (07) :3664-3669
[10]   Challenges for Rechargeable Li Batteries [J].
Goodenough, John B. ;
Kim, Youngsik .
CHEMISTRY OF MATERIALS, 2010, 22 (03) :587-603