Design and fabrication of pumpless small direct methanol fuel cells for portable applications

被引:186
作者
Shimizu, T
Momma, T
Mohamedi, M
Osaka, T
Sarangapani, S
机构
[1] Waseda Univ, Grad Sch Sci & Engn, Shinjuku Ku, Tokyo 1698555, Japan
[2] Japan Sci & Technol Agcy, CREST, Tokyo 1028666, Japan
[3] ICET Inc, Unit 2, Norwood, MA 02062 USA
关键词
DMFC; passive fuel cells; ambient temperature; small-scale application; portable; nation;
D O I
10.1016/j.jpowsour.2004.06.008
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This work studied the design, fabrication, and performance evaluation of a 36 cm(2), passive, air-breathing, room-temperature, direct methanol fuel cell (DMFC). The cell is completely passive with no external pumps or other ancillary devices. It takes oxygen from the surrounding air, and the methanol solution is stored in a built-in reservoir. The fuel cell runs successfully with methanol concentration ranging from 0.5 to 4 M. It produced a power density of 11 mW cm(-2) reached with 4 M methanol at current densities as high as 36 mA cm(-2) and at a voltage of 0.3. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:277 / 283
页数:7
相关论文
共 19 条
[1]   Mixed-reactant, strip-cell direct methanol fuel cells [J].
Barton, SC ;
Patterson, T ;
Wang, E ;
Fuller, TF ;
West, AC .
JOURNAL OF POWER SOURCES, 2001, 96 (02) :329-336
[2]   Water-neutral micro direct-methanol fuel cell (DMFC) for portable applications [J].
Blum, A ;
Duvdevani, T ;
Philosoph, M ;
Rudoy, N ;
Peled, E .
JOURNAL OF POWER SOURCES, 2003, 117 (1-2) :22-25
[3]   Materials and processes for small fuel cells [J].
Chang, H ;
Kim, JR ;
Cho, JH ;
Kim, HK ;
Choi, KH .
SOLID STATE IONICS, 2002, 148 (3-4) :601-606
[4]   International activities in DMFC R&D:: status of technologies and potential applications [J].
Dillon, R ;
Srinivasan, S ;
Aricò, AS ;
Antonucci, V .
JOURNAL OF POWER SOURCES, 2004, 127 (1-2) :112-126
[5]   Replacing the battery in portable electronics [J].
Dyer, CK .
SCIENTIFIC AMERICAN, 1999, 281 (01) :88-93
[6]  
Jung DH, 1998, J POWER SOURCES, V71, P169, DOI 10.1016/S0378-7753(97)02793-6
[7]   Miniature fuel cells fabricated on silicon substrates [J].
Kelley, SC ;
Deluga, GA ;
Smyrl, WH .
AICHE JOURNAL, 2002, 48 (05) :1071-1082
[8]   Miniature methanol/air polymer electrolyte fuel cell [J].
Kelley, S.C. ;
Deluga, G.A. ;
Smyrl, W.H. .
2000, IEEE, Pennington, NJ, United States (03)
[9]   Development and characterization of a silicon-based micro direct methanol fuel cell [J].
Lu, GQ ;
Wang, CY ;
Yen, TJ ;
Zhang, X .
ELECTROCHIMICA ACTA, 2004, 49 (05) :821-828
[10]   Miniature fuel cells for portable power: Design considerations and challenges [J].
Maynard, HL ;
Meyers, JP .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2002, 20 (04) :1287-1297