Photoinduced intrarotaxane electron transfer between zinc porphyrin and [60]fullerene in benzonitrile

被引：113

作者：

Watanabe, N

Kihara, N

Furusho, Y

Takata, T

Araki, Y

Ito, O

机构：

[1] Osaka Prefecture Univ, Dept Appl Chem, Grad Sch Engn, Sakai, Osaka 5998531, Japan

[2] Tohoku Univ, CREST, JST, Inst Multidisciplinary Res Adv Mat,Aoba Ku, Sendai, Miyagi 9808577, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 06期

关键词：

charge transfer; fluorescence; fullerenes; porphyrinoids; rotaxanes;

D O I：

10.1002/anie.200390188

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A through-space superexchange mechanism appears to be responsible for charge recombination (CR) following photoexcitation and charge separation (CS) in rotaxanes containing zinc porphyrin and C60 moieties (see picture), as suggested by the low activation energy of this process. Furthermore, the charge-separated state is relatively long-lived.

引用

页码：681 / 683

页数：3

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