Block and star block copolymers by mechanism transformation.: VIII Synthesis and characterization of triblock poly(LLA-b-St-b-MMA) by combination of ATRP and ROP

被引：68

作者：

Tao, L ^{[1
]}

Luan, B ^{[1
]}

Pan, CY ^{[1
]}

机构：

[1] Univ Sci & Technol China, Dept Polymer Sci & Engn, Hefei 230026, Peoples R China

来源：

POLYMER | 2003年 / 44卷 / 04期

基金：

中国国家自然科学基金;

关键词：

atom transfer radical polymerization; block copolymer; bifunctional initiator;

D O I：

10.1016/S0032-3861(02)00870-4

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Block copolymers, poly(LLA-b-St)s and triblock copolymes, poly(LLA-b-St-b-MMA)s have been synthesized by the combination of the atom transfer radical polymerization (ATRP) with ring-opening polymerization (ROP) using bifunctional initiator (beta-hydroxylethyl alpha-bromoisobutyrate (HEBIB) without intermediate function transformation. The molecular weight (MW) and the molecular weight distribution (MWD) can be controlled. The structures of the copolymers were confirmed by H-1 NMR spectroscopy and GPC. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：1013 / 1020

页数：8

共 58 条

[1]

Acar MH, 1999, MACROMOL CHEM PHYSIC, V200, P1094, DOI 10.1002/(SICI)1521-3935(19990501)200:5<1094::AID-MACP1094>3.0.CO

[2]

2-I

[3] Amphiphilic stars and dendrimer-like architectures based on poly(ethylene oxide) and polystyrene [J].

Angot, B ;

Taton, D ;

Gnanou, Y .

MACROMOLECULES, 2000, 33 (15) :5418-5426

[4] SYNTHESIS OF BLOCK COPOLYMERS WITH POLY(METHYL METHACRYLATE) - P(B-B-MMA), P(EB-B-MMA), P(S-B-B-B-MMA) AND P(S-B-EB-B-MMA) [J].

AUSCHRA, C ;

STADLER, R .

POLYMER BULLETIN, 1993, 30 (03) :257-264

[5] Synthesis and microphase separation of linear triblock terpolymers of polystyrene, high 1,4-polybutadiene, and high 3,4-polyisoprene [J].

Avgeropoulos, A ;

Paraskeva, S ;

Hadjichristidis, N ;

Thomas, EL .

MACROMOLECULES, 2002, 35 (10) :4030-4035

[6] Block copolymers - Designer soft materials [J].

Bates, FS ;

Fredrickson, GH .

PHYSICS TODAY, 1999, 52 (02) :32-38

[7]

BRINDER K, 1994, ADV POLYM SCI, V112, P181

[8] Block copolymers of styrene and p-acetoxystyrene with polyisobutylene by combination of living carbocationic and atom transfer radical polymerizations [J].

Chen, XY ;

Ivan, B ;

Kops, J ;

Batsberg, W .

MACROMOLECULAR RAPID COMMUNICATIONS, 1998, 19 (11) :585-589

[9] Living free-radical polymerization by reversible addition-fragmentation chain transfer: The RAFT process [J].

Chiefari, J ;

Chong, YK ;

Ercole, F ;

Krstina, J ;

Jeffery, J ;

Le, TPT ;

Mayadunne, RTA ;

Meijs, GF ;

Moad, CL ;

Moad, G ;

Rizzardo, E ;

Thang, SH .

MACROMOLECULES, 1998, 31 (16) :5559-5562

[10]

Coca S, 1997, J POLYM SCI POL CHEM, V35, P3595, DOI 10.1002/(SICI)1099-0518(19971130)35:16<3595::AID-POLA27>3.0.CO

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