BaGe5: A New Type of Intermetallic Clathrate

被引：37

作者：

Aydemir, Umut ^{[1
]}

Akselrud, Lev ^{[1
]}

Carrillo-Cabrera, Wilder ^{[1
]}

Candolfi, Christophe ^{[1
]}

Oeschler, Niels ^{[1
]}

Baitinger, Michael ^{[1
]}

Steglich, Frank ^{[1
]}

Grin, Yuri ^{[1
]}

机构：

[1] Max Planck Inst Chem Phys Fester Stoffe, D-01187 Dresden, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 32期

关键词：

CRYSTAL-STRUCTURE; BA6GE25; BA8GE43;

D O I：

10.1021/ja104197c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

BaGe5 constitutes a new type of intermetallic clathrate obtained by decomposition of clathrate-I Ba8Ge43 square(3) at low temperatures. The crystal structure consists of characteristic layers interconnected by covalent bonds. BaGe5 is a semiconducting Zintl phase.

引用

页码：10984 / 10985

页数：2

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