Synthesis, characterization and aggregation behavior of Ni(II) and Zn(II) phthalocyanines with peripheral monoazacrown ethers

被引:11
作者
Atilla, D
Ahsen, V
机构
[1] Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Turkey
[2] TUBITAK, Marmara Res Ctr, Mat & Chem Technol Res Inst, TR-41400 Gebze, Turkey
关键词
phthalocyanine; azacrown ether; aggregation; nickel; zinc;
D O I
10.1142/S1088424602000737
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis of metallo derivatives (Ni, Zn) of phthalocyanines (pcs) obtained from 4,5-dicyanobenzomonoazacrown ether substituted with long alkyl chains (5a-d) are described. The new compounds have been characterized by elemental analysis, H-1, C-13 NMR, MS, IR and UV-vis spectroscopy techniques. The aggregation properties and alkali metal interaction of the pcs (6a-d and 7a-d) were investigated. Copyright (C) 2002 Society of Porphyrins & Phthalocyanines.
引用
收藏
页码:593 / 601
页数:9
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