Poly(phenylene sulfide-phenyleneamine) (PPSA): The first hybrid structure of poly(phenylene sulfide) and polyaniline

被引：43

作者：

Leuninger, J ^{[1
]}

Wang, CS ^{[1
]}

Soczka-Guth, T ^{[1
]}

Enkelmann, V ^{[1
]}

Pakula, T ^{[1
]}

Mullen, K ^{[1
]}

机构：

[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany

来源：

MACROMOLECULES | 1998年 / 31卷 / 06期

关键词：

D O I：

10.1021/ma9713668

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

High molecular weight poly(phenylene sulfide-phenyleneamine) (PPSA, M-n = 1.5 x 10(5)) was synthesized via a poly(sulfonium) cation through an acid-induced polycondensation reaction of [4-(methylsulfinyl)phenyl]phenylamine. To our best knowledge, the new polymer represents the first hybrid structure of poly(phenylene sulfide) (PPS) and polyaniline (PAni). In contrast to these two intensively studied polymers, PPSA exhibits a high solubility in solvents, such as THF, DMF, DMSO, and NMP. DSC and X-ray studies revealed the completely amorphous structure of PPSA, which cannot even be influenced by annealing the polymer at temperatures above the glass transition. Furthermore, electronic properties were studied by cyclic voltammetry, and preliminary doping experiments for elucidating the electrical conductivity were carried out.

引用

页码：1720 / 1727

页数：8

共 46 条

[1] POLYANILINE - SOLUTIONS, FILMS AND OXIDATION-STATE [J].