Indium-mediated formation of propargyl ketones from aldehydes or acyl chlorides

被引：30

作者：

Augé, J ^{[1
]}

Lubin-Germain, N ^{[1
]}

Seghrouchni, L ^{[1
]}

机构：

[1] UCP, ESCOM, CNRS, UMR 8123, F-95031 Cergy Pontoise, France

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 04期

关键词：

indium; propargyl ketone; alkynylation; Barbier reaction; Oppenauer oxidation;

D O I：

10.1016/S0040-4039(02)02635-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Propargyl ketones were prepared from aldehydes via an indium-mediated alkynylation reaction followed by an indium-mediated Oppenauer oxidation. They were also obtained via an indium-mediated alkynylation of the relevant acyl chlorides. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：819 / 821

页数：3

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