Chemoselective aldehyde addition of zinc carbenoid generated from tribromofluoromethane

被引：6

作者：

Hata, T ^{[1
]}

Kitagawa, H ^{[1
]}

Shimizu, M ^{[1
]}

Hiyama, T ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Sakyo Ku, Kyoto 6068501, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2000年 / 73卷 / 07期

关键词：

D O I：

10.1246/bcsj.73.1691

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of tribromofluoromethane with diethylzinc in DMF at -60 degrees C generated a zinc carbenoid reagent, which reacted with aldehydes RCHO chemoselectively to give RCH(OH)CFBr2 in moderate-to-good yields.

引用

页码：1691 / 1695

页数：5

共 44 条

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