Sintering behaviour of CuO-doped SnO2

被引：36

作者：

Lalande, J ^{[1
]}

Ollitrault-Fichet, R ^{[1
]}

Boch, P ^{[1
]}

机构：

[1] Ecole Super Phys & Chim Ind, F-75005 Paris, France

来源：

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY | 2000年 / 20卷 / 14-15期

关键词：

CuO; microstructure-final; sintering; SnO2;

D O I：

10.1016/S0955-2219(00)00153-9

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The sintering behaviour of CuO-doped SnO2 ceramics was studied. Additive-free SnO2 materials do not densify after heat treatment to 1400 degreesC, whereas materials doped with 0.5-0.75 wt.% CuO densify to 98% of theoretical. Copper oxides (CuO/Cu2O) experience reduction and re-oxidation phenomena. There is no evidence of high vaporisation of SnO2, nor of liquid formation at low temperature (<1000<degrees>C) in the CuO-SnO2 system. This suggests that CuO acts by grain-boundary mechanisms. (C) 2000 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：2415 / 2420

页数：6

共 22 条

[1]

Ahn JP, 1997, J AM CERAM SOC, V80, P2165

[2] Low-temperature sintering of 0.99 SnO2 0.01 CuO: Influence of copper surface diffusion [J].

Bonnet, JP ;

Dolet, N ;

Heintz, JM .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1996, 16 (11) :1163-1169

[3]

Brook R.J., 1976, Treatise on Materials Science & Technology, V9, P331

[4]

Cerri JA, 1996, J AM CERAM SOC, V79, P799, DOI 10.1111/j.1151-2916.1996.tb07949.x

[5] EFFECT OF HEATING RATE ON SINTERING AND COARSENING [J].

CHU, MY ;

RAHAMAN, MN ;

DEJONGHE, LC ;

BROOK, RJ .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1991, 74 (06) :1217-1225

[6] SINTERING MECHANISMS OF 0.99-SNO2-0.01-CUO MIXTURES [J].

DOLET, N ;

HEINTZ, JM ;

RABARDEL, L ;

ONILLON, M ;

BONNET, JP .

JOURNAL OF MATERIALS SCIENCE, 1995, 30 (02) :365-368

[7]

Dolet N., 1992, Journal of the European Ceramic Society, V9, P19, DOI 10.1016/0955-2219(92)90072-L

[8]

DOLET N, 1992, THESIS U BORDEAUX 1

[9]

Duvigneaud PH, 1980, SCI SINTER, V12, P287

[10]

GADALLA AMM, 1963, BRIT CERAM T, V62, P57

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