Dominant factors on the micellization of BnEmBn-Type triblock copolymers in aqueous solution

被引:57
作者
Liu, TB
Zhou, ZK
Wu, CH
Nace, VM
Chu, B [1 ]
机构
[1] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA
[2] Tamkang Univ, Dept Chem, Tamsui 25137, Taiwan
[3] Dow Chem Co, Texas Operat, Freeport, TX 77451 USA
[4] SUNY Stony Brook, Dept Mat Sci & Engn, Stony Brook, NY 11794 USA
来源
JOURNAL OF PHYSICAL CHEMISTRY B | 1998年 / 102卷 / 16期
关键词
D O I
10.1021/jp980139k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The micellization parameters of a series of oxyethylene/oxybutylene (BnEmBn) triblock copolymers (B4E40B4, B5E39B5, B5E91B5, B6E46B6, B7E22B7, B7E40B7, B10E271B10, and B12E260B12) were summarized to obtain collective conclusions on the dominant factors that affect the micellization of such sort of triblock copolymers in aqueous solution. The effects of the block lengths of both the hydrophobic end B blocks and the hydrophilic middle E block on the critical micellar concentrations, the association numbers, the second virial coefficients of micelles, the enthalpy of micellization, the hydrodynamic radius, and the intermicellar cross-linking are discussed. It was found that the micellization was mainly determined by the B block length while the micellar size and the intermicellar structure were influenced greatly by the E block length. The scaling theory that was derived from diblock copolymer micelle models can also be used in triblock copolymer miceller systems.
引用
收藏
页码:2875 / 2882
页数:8
相关论文
共 31 条
[1]   MICELLIZATION OF POLY(ETHYLENE OXIDE)-POLY(PROPYLENE OXIDE)-POLY(ETHYLENE OXIDE) TRIBLOCK COPOLYMERS IN AQUEOUS-SOLUTIONS - THERMODYNAMICS OF COPOLYMER ASSOCIATION [J].
ALEXANDRIDIS, P ;
HOLZWARTH, JF ;
HATTON, TA .
MACROMOLECULES, 1994, 27 (09) :2414-2425
[2]  
AMSTRONG JK, 1993, J PHYS CHEM-US, V97, P3904
[3]  
ANOS NM, 1993, PHYSICO CHEM PROPERT
[4]   MICELLE FORMATION OF BAB TRIBLOCK COPOLYMERS IN SOLVENTS THAT PREFERENTIALLY DISSOLVE THE A-BLOCK [J].
BALSARA, NP ;
TIRRELL, M ;
LODGE, TP .
MACROMOLECULES, 1991, 24 (08) :1975-1986
[5]   STYRENE BUTADIENE BLOCK COPOLYMER MICELLES IN HEPTANE [J].
BLUHM, TL ;
WHITMORE, MD .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1985, 63 (01) :249-252
[6]  
CHU B, 1996, NONIONIC SURFACTANTS, pCH3
[7]  
Dow Chemical Co. Technical Literature B-Series, 1994, TECHN LIT B
[8]   POLYMERIC MICELLES - A STAR MODEL [J].
HALPERIN, A .
MACROMOLECULES, 1987, 20 (11) :2943-2946
[9]   Cloud-point temperatures of BnEmBn and PnEmPn type triblock copolymers in aqueous solution [J].
Liu, TB ;
Nace, VM ;
Chu, B .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (41) :8074-8078
[10]   Self-assembly of poly(oxybutylene)-poly(oxyethylene)-poly(oxybutylene) (B6E46B6) triblock copolymer in aqueous solution [J].
Liu, TB ;
Zhou, ZK ;
Wu, CH ;
Chu, B ;
Schneider, DK ;
Nace, VM .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (43) :8808-8815