HCl-catalyzed stereoselective Mannich reaction in H2O-SDS system

被引：104

作者：

Akiyama, T ^{[1
]}

Matsuda, K ^{[1
]}

Fuchibe, K ^{[1
]}

机构：

[1] Gakushuin Univ, Dept Chem, Toshima Ku, Tokyo 1718588, Japan

来源：

SYNLETT | 2005年 / 02期

关键词：

Mannich reactions; Bronsted acid; water; amines; surfactant;

D O I：

10.1055/s-2004-836062

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

HCl-catalyzed Mannich reaction of cyclic ketone, aromatic aldehyde, and aromatic amine proceeded smoothly in water in the presence of SDS to afford the corresponding beta-amino ketone with high anti selectivity.

引用

页码：322 / 324

页数：3

共 30 条

[1] Mannich-type reaction catalyzed by HBF4 in water:: Effect of the loading of surfactant
Akiyama, T
Itoh, J
Fuchibe, K
[J]. SYNLETT, 2002, (08) : 1269 - 1272
[2] Akiyama T, 2002, ADV SYNTH CATAL, V344, P338, DOI 10.1002/1615-4169(200206)344:3/4<338::AID-ADSC338>3.0.CO
[3] 2-O
[4] A highly stereo-divergent Mannich-type reaction catalyzed by Bronsted acid in aqueous media
Akiyama, T
Takaya, J
Kagoshima, H
[J]. TETRAHEDRON LETTERS, 2001, 42 (24) : 4025 - 4028
[5] Bronsted acid-catalyzed aza Diels-Alder reaction of Danishefsky's diene with aldimine generated in situ from aldehyde and amine in aqueous media
Akiyama, T
Takaya, J
Kagoshima, H
[J]. TETRAHEDRON LETTERS, 1999, 40 (44) : 7831 - 7834
[6] Akiyama T, 1999, SYNLETT, P1426
[7] HBF4 catalyzed Mannich-type reaction in aqueous media
Akiyama, T
Takaya, J
Kagoshima, H
[J]. SYNLETT, 1999, (07) : 1045 - 1048
[8] [Anonymous], [No title captured]
[9] Arend M, 1998, ANGEW CHEM INT EDIT, V37, P1044, DOI 10.1002/(SICI)1521-3773(19980504)37:8<1044::AID-ANIE1044>3.0.CO
[10] 2-E

← 1 2 3 →