Linear alcohols adsorbed on graphite from the liquid

被引:8
作者
Clarke, S
Messe, L
Whitehead, C
Inaba, A
Thomas, R
Arnold, T
机构
[1] Dept Chem, Cambridge, England
[2] BP Inst, Cambridge, England
[3] Osaka Univ, Grad Sch Sci, Dept Chem, Osaka, Japan
[4] Phys & Theoret Chem Lab, Oxford, England
来源
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING | 2002年 / 74卷 / Suppl 1期
关键词
Adsorption - Differential scanning calorimetry - Graphite - Monolayers - Neutron diffraction;
D O I
10.1007/s003390101191
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A combination of sensitive calorimetry and neutron diffraction data is presented demonstrating the formation of solid monolayers for linear alcohols (c5 to c19) adsorbed from their liquids to a graphite surface. The results reveal a significant odd-even variation in the monolayer melting points, much bigger than the bulk alcohols, that appears to be structural in origin.
引用
收藏
页码:S1072 / S1073
页数:2
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