Self-assembled monolayers applications for the development of electrochemical sensors.

被引：24

作者：

Freire, RS ^{[1
]}

Pessoa, CA ^{[1
]}

Kubota, LT ^{[1
]}

机构：

[1] Univ Estadual Campinas, Inst Quim, BR-13084971 Campinas, SP, Brazil

来源：

QUIMICA NOVA | 2003年 / 26卷 / 03期

关键词：

chemically modified electrodes; self-assembled monolayers; electrochemical sensors;

D O I：

10.1590/S0100-40422003000300016

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

SELF-ASSEMBLED MONOLAYERS APPLICATIONS FOR THE DEVELOPMENT OF ELECTROCHEMICAL SENSORS. Self-assembled monolayers (SAMs) modified electrodes exhibit unique behavior that can greatly benefit electrochemical sensing. This brief review highlights the applications of SAM modified electrodes in electroanalytical chemistry. After a general introduction, which includes the approaches for SAM development, different electrochemical systems for detecting inorganic and organic species are described and discussed. Special attention to the coupling of biological sensing element to the SAM is given, which can selectively recognize the analyte. Future prospects are also evaluated.

引用

页码：381 / 389

页数：9

共 143 条

[1]

Alexander PW, 2000, ELECTROANAL, V12, P343

[2] A study of L-cysteine adsorption on gold via electrochemical desorption and copper(II) ion complexation [J].

Arrigan, DWM ;

Le Bihan, L .

ANALYST, 1999, 124 (11) :1645-1649

[3] NAD(+)-dependent enzyme electrodes: Electrical contact of cofactor-dependent enzymes and electrodes [J].

Bardea, A ;

Katz, E ;

Buckmann, AF ;

Willner, I .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (39) :9114-9119

[4] Coupling of acid-base and redox functions in mixed sulfide monolayers on gold [J].

Beulen, MWJ ;

van Veggel, FCJM ;

Reinhoudt, DN .

CHEMICAL COMMUNICATIONS, 1999, (06) :503-504

[5] An AFM study of the effects of silanization temperature, hydration, and annealing on the nucleation and aggregation of condensed OTS domains on mica [J].

Britt, DW ;

Hlady, V .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1996, 178 (02) :775-784

[6] Biomedical aspects of electrochemical methods of analysis [J].

Budnikov, GK .

JOURNAL OF ANALYTICAL CHEMISTRY, 2000, 55 (11) :1014-1023

[7] The impact of solution agglomeration on the deposition of self-assembled monolayers [J].

Bunker, BC ;

Carpick, RW ;

Assink, RA ;

Thomas, ML ;

Hankins, MG ;

Voigt, JA ;

Sipola, D ;

de Boer, MP ;

Gulley, GL .

LANGMUIR, 2000, 16 (20) :7742-7751

[8] Self-assembled monolayers as a tunable platform for biosensor applications [J].

Chaki, NK ;

Vijayamohanan, K .

BIOSENSORS & BIOELECTRONICS, 2002, 17 (1-2) :1-12

[9]

CHENG CA, 1995, ANAL CHEM, V67, P2767

[10] Permselectivity sensitivity, and amperometric pH sensing at thioctic acid monolayer microelectrodes [J].

Cheng, Q ;

BrajterToth, A .

ANALYTICAL CHEMISTRY, 1996, 68 (23) :4180-4185

← 1 2 3 4 5 6 7 8 9 10 →