[Bis(2-mercapto-1-methylimidazol-3-yl)-borato](triphenylphosphine)gold(I)

被引:13
作者
Mohamed, AA
Rabinovich, D
Fackler, JP
机构
[1] Texas A&M Univ, Dept Chem, Mol Struct & Bonding Lab, College Stn, TX 77842 USA
[2] Univ N Carolina, Charlotte, NC 28223 USA
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2002年 / 58卷
关键词
D O I
10.1107/S1600536802020512
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The Au atom in the title complex, [Au(C8H12BN4S2)(C18H15P)], is coordinated by two S (thione) atoms and one phosphine ligand in a distorted trigonal environment. The gold center is displaced by 0.048 (1) Angstrom from the coordination mean plane. The Au-S-thione distances are 2.3511 (8) and 2.8155 (12) Angstrom, and the Au-P distance is 2.2557 (12) Angstrom.
引用
收藏
页码:M726 / M727
页数:2
相关论文
共 13 条
[1]   AN EMPIRICAL CORRECTION FOR ABSORPTION ANISOTROPY [J].
BLESSING, RH .
ACTA CRYSTALLOGRAPHICA SECTION A, 1995, 51 :33-38
[2]  
*BRUK AXS INC, 1999, SAINT VERS 6 02
[3]  
*BRUK AXS INC, 2001, SMART VERS 5 618
[4]   Hydrotris(methimazolyl)borate, a soft analogue of hydrotris(pyrazolyl)borate. Preparation and crystal structure of a novel zinc complex [J].
Garner, M ;
Reglinski, J ;
Cassidy, I ;
Spicer, MD ;
Kennedy, AR .
CHEMICAL COMMUNICATIONS, 1996, (16) :1975-1976
[5]   Modeling the catalytic site of liver alcohol dehydrogenase: Synthesis and structural characterization of a [bis(thioimidazolyl)(pyrazolyl)hydroborato]zinc complex, [HB(tim(Me))(2)pz]ZnI [J].
Kimblin, C ;
Hascall, T ;
Parkin, G .
INORGANIC CHEMISTRY, 1997, 36 (25) :5680-5681
[6]  
Parkin G., 1995, ADV INORG CHEM, V42, P291
[7]   New phosphino silver(I) derivatives of hydrotris(3-methyl-2-thioxo-1-imidazolyl)borate. X-ray crystal structure of tricyclohexylphosphine-silver(I)-hydrotris(3-methyl-2-thioxo-1-imidazolyl)borate [J].
Santini, C ;
Pettinari, C ;
Lobbia, GG ;
Spagna, R ;
Pellei, M ;
Vallorani, F .
INORGANICA CHIMICA ACTA, 1999, 285 (01) :81-88
[8]   Syntheses and spectroscopic and structural characterization of silver(I) complexes containing tertiary phosphines and hydrotris(pyrazol-1-yl)-, hydrotris(4-bromopyrazol-1-yl)-, hydrotris(3,5-dimethypyrazol-1-yl)-, and hydrotris(3-methyl-2-thioxo-1-imidazolyl)borates [J].
Santini, C ;
Lobbia, GG ;
Pettinari, C ;
Pellei, M ;
Valle, G ;
Calogero, S .
INORGANIC CHEMISTRY, 1998, 37 (05) :890-900
[9]  
Sheldrick GM, 2015, ACTA CRYSTALLOGR C, V71, P3, DOI [10.1107/S2053229614024218, 10.1107/S0108767307043930]
[10]   PHASE ANNEALING IN SHELX-90 - DIRECT METHODS FOR LARGER STRUCTURES [J].
SHELDRICK, GM .
ACTA CRYSTALLOGRAPHICA SECTION A, 1990, 46 :467-473