Catalysts for the production of fine chemicals - Production of food emulsifiers, monoglycerides, by glycerolysis of fats with solid base catalysts

被引：246

作者：

Corma, A ^{[1
]}

Iborra, S ^{[1
]}

Miquel, S ^{[1
]}

Primo, J ^{[1
]}

机构：

[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain

来源：

JOURNAL OF CATALYSIS | 1998年 / 173卷 / 02期

关键词：

D O I：

10.1006/jcat.1997.1930

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Glycerolysis of triolein and rapeseed oil were carried out with base catalysts such as Cs-MCM-41, Cs-Sepiolite, MgO, and calcined hydrotalcites with different Al/Al + Mg ratios. A wide range of basicities were covered in order to extract active hydrogens with pKa values from 9 to 16. MgO and hydrotalcites with low Al content, basic enough to extract protons from aliphatic alcohols such as glycerol, are active and selective catalysts for glycerolysis. By optimizing the main process variables, such as temperature and the glycerol/oil ratio it is possible to obtain a high yield of monoglycerides as well as to meet the quality requirements established by the European Union. (C) 1998 Academic Press.

引用

页码：315 / 321

页数：7

共 29 条

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