Rhodium-catalyzed intramolecular alkyne-carbodiimide Pauson-Khand-type reaction

被引:52
作者
Saito, Takao [1 ]
Sugizaki, Katsuya [1 ]
Otani, Takashi [1 ]
Suyama, Toshiyuki [1 ]
机构
[1] Tokyo Univ Sci, Fac Sci, Dept Chem, Shinjuku Ku, Tokyo 1628601, Japan
关键词
D O I
10.1021/ol063123i
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An efficient, Rh-catalyzed intramolecular Pauson-Khand-type carbonylation of alkyne-carbodiimides leading to 4,5-dihydro-1H-pyrrolo[2,3-b]pyrrolin-2-ones and 1H-pyrrolo[2,3-b]indol-2-ones is described.
引用
收藏
页码:1239 / 1241
页数:3
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