A novel synthesis of chiral DBU/DBN-related molecules for use in asymmetric base catalysis

被引：9

作者：

Kotsuki, H ^{[1
]}

Sugino, A ^{[1
]}

Sakai, H ^{[1
]}

Yasuoka, H ^{[1
]}

机构：

[1] Kochi Univ, Fac Sci, Lab Nat Prod Synthesis, Kochi 7808520, Japan

来源：

HETEROCYCLES | 2000年 / 53卷 / 11期

关键词：

D O I：

10.3987/COM-00-9036

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of sterically hindered chiral DBU/DBN-related molecules (6) from (+)-camphor lactam (1) is described. The value of the products as chiral organic base catalysts is exemplified by their use in asymmetric Michael addition reactions of beta -keto ester (7).

引用

页码：2561 / +

页数：8

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