Synthesis of xLi2MnO3•(1-x)LiMO2 (M = Cr, Mn, Co, Ni) nanocomposites and their electrochemical properties

被引：39

作者：

Kim, Donghan ^{[1
]}

Gim, Jihyeon ^{[1
]}

Lim, Jinsub ^{[1
]}

Park, Sangjun ^{[1
]}

Kim, Jaekook ^{[1
]}

机构：

[1] Chonnam Natl Univ, Dept Mat Sci Engn, Kwangju 500757, South Korea

来源：

MATERIALS RESEARCH BULLETIN | 2010年 / 45卷 / 03期

基金：

新加坡国家研究基金会;

关键词：

Inorganic compounds; Intercalation reactions; Electrochemical measurements; Electrochemical properties; RECHARGEABLE LITHIUM BATTERIES; ELECTRODE MATERIALS; ION BATTERIES; CATHODES;

D O I：

10.1016/j.materresbull.2009.12.027

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A series of 0.4Li(2)MnO(3)center dot 0.6LiMO(2) (M = Ni1/3Co1/3Mn1/3 and Ni1/3Cr1/3Mn1/3) cathode materials are prepared by a co-precipitation method with subsequent quenching. Crystal structures of samples are investigated by X-ray diffraction and electron diffraction, which show a co-existence of rhombohedral and monoclinic structures indicating nanocomposite characteristics of the sample of 0.4Li(2)MnO(3)center dot 0.6Li Ni1/3Cr1/3Mn1/3O2. The average particle size distributions of the powders are analyzed to be an order 400 and 100 nm. The 0.4Li(2)MnO(3)center dot 0.6LiMO(2) (M=Ni1/3CO1/3Mn1/3 and Ni1/3Cr1/3Mn1/3) electrodes, which consist of a well balanced partial phases of rhombohedral and monoclinic can deliver a high reversible capacity of 220-230 mAh/g during an extended cycling. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：252 / 255

页数：4

共 9 条

[1] High capacity, temperature-stable lithium aluminum manganese oxide cathodes for rechargeable batteries
Chiang, YM
Sadoway, DR
Jang, YI
Huang, BY
Wang, HF
[J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 1999, 2 (03) : 107 - 110
[2] Synthesis and characterization of LiAl1/4Ni3/4O2 (R(3)over-bar-m) for lithium-ion (shuttlecock) batteries
Ohzuku, T
Ueda, A
Kouguchi, M
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (12) : 4033 - 4039
[3] Phospho-olivines as positive-electrode materials for rechargeable lithium batteries
Padhi, AK
Nanjundaswamy, KS
Goodenough, JB
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (04) : 1188 - 1194
[4] Synthesis and materials characterization of Li2MnO3-LiCrO2 system nanocomposite electrode materials
Park, C. W.
Kim, S. H.
Mangani, I. Ruth
Lee, J. H.
Boo, S.
Kim, J.
[J]. MATERIALS RESEARCH BULLETIN, 2007, 42 (07) : 1374 - 1383
[5] Structural and electrochemical properties of Li[Cr0.29Li0.24Mn0.47]O2 nanocomposite electrode for lithium-ion batteries
Park, Chan-Woo
Kim, Jaekook
[J]. CHEMISTRY LETTERS, 2006, 35 (08) : 886 - 887
[6] LITHIUM MANGANESE OXIDES FROM LI2MN03 FOR RECHARGEABLE LITHIUM BATTERY APPLICATIONS
ROSSOUW, MH
THACKERAY, MM
[J]. MATERIALS RESEARCH BULLETIN, 1991, 26 (06) : 463 - 473
[7] Issues and challenges facing rechargeable lithium batteries
Tarascon, JM
Armand, M
[J]. NATURE, 2001, 414 (6861) : 359 - 367
[8] Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries
Thackeray, Michael M.
Kang, Sun-Ho
Johnson, Christopher S.
Vaughey, John T.
Benedek, Roy
Hackney, S. A.
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (30) : 3112 - 3125
[9] Effect of surface modifications on the layered solid solution cathodes (1-z) Li[Li1/3Mn2/3]O2-(z) Li[Mn0.5-yNi0.5-yCo2y]O2
Wu, Y.
Manthiram, A.
[J]. SOLID STATE IONICS, 2009, 180 (01) : 50 - 56

← 1 →