Expanded scope in ethylene-alkyne cross-metathesis: Coordinating heteroatom functionality at the propargylic position

被引：105

作者：

Smulik, JA ^{[1
]}

Diver, ST ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 15期

关键词：

D O I：

10.1021/ol006035l

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The Grubbs 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene-substituted ruthenium complex 1 catalyzed ethylene-alkyne cross-metathesis and was shown to tolerate free hydroxyl groups and coordinating functionality at the propargylic and homopropargylic positions, Hindered and enantiomerically enriched 1-substituted alkynes also react efficiently under the reported conditions.

引用

页码：2271 / 2274

页数：4

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