Analytical solution of the elastic Boltzmann transport equation in an infinite uniform medium using cumulant expansion

被引:15
作者
Cai, W [1 ]
Lax, M
Alfano, RR
机构
[1] CUNY City Coll, Dept Phys, New York State Ctr Adv Technol Ultrafast Photon M, Inst Ultrafast Spect & Lasers, New York, NY 10031 USA
[2] CUNY City Coll, Grad Ctr, New York, NY 10031 USA
来源
JOURNAL OF PHYSICAL CHEMISTRY B | 2000年 / 104卷 / 16期
关键词
D O I
10.1021/jp994447+
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We study the analytical solution of the time-dependent elastic Boltzmann transport equation in an infinite uniform isotropic medium with an arbitrary phase function. We calculate (1) the exact distribution in angle, (2) the spatial cumulants at any angle, exact up to an arbitrary high order n. At the second order, n = 2, an analytical, hence extremely useful combined distribution in position and angle, is obtained as a function of time. This distribution is Gaussian in position, but not in angle. The average center and spread of the half-width are exact. By the central limit theorem the complete distribution approaches this Gaussian distribution as the number of collisions (or time) increases. The center of this distribution advances in time, and an ellipsoidal contour that grows and changes shape provides a clear picture of the time evolution of the particle migration from near ballistic, through snake-like, and into the final diffusive regime. This second-order cumulant approximation also provides the correct ballistic limit. Algebraic expressions for the nth order cumulants are provided. The number of terms grows rapidly with n, but our expressives are recursive and easily automated.
引用
收藏
页码:3996 / 4000
页数:5
相关论文
共 14 条
[1]  
Bohren C. F., 1998, ABSORPTION SCATTERIN
[2]  
Brink D, 1962, ANGULAR MOMENTUM
[3]  
CASE KM, 1967, LINEAR TRANSPORT THE
[4]  
Chandrasekhar S, 1950, RAD TRANSFER
[5]  
Duderstadt J. J., 1979, Transport theory
[6]   THE RADIATION THEORIES OF TOMONAGA, SCHWINGER, AND FEYNMAN [J].
DYSON, FJ .
PHYSICAL REVIEW, 1949, 75 (03) :486-502
[7]   AN OPERATOR CALCULUS HAVING APPLICATIONS IN QUANTUM ELECTRODYNAMICS [J].
FEYNMAN, RP .
PHYSICAL REVIEW, 1951, 84 (01) :108-128
[8]  
HAUGE EH, 1974, TRANSPORT PHENOMENA, P337
[9]   DIFFUSION OF LIGHT IN TURBID MATERIAL [J].
ISHIMARU, A .
APPLIED OPTICS, 1989, 28 (12) :2210-2215
[10]   FLUCTUATIONS FROM THE NONEQUILIBRIUM STEADY STATE [J].
LAX, M .
REVIEWS OF MODERN PHYSICS, 1960, 32 (01) :25-64