Double elimination protocol for access to pyridine-containing arylene-ethynylenes

被引:20
作者
Orita, A [1 ]
Nakano, T [1 ]
Yokoyama, T [1 ]
Babu, G [1 ]
Otera, J [1 ]
机构
[1] Okayama Univ Sci, Dept Appl Chem, Okayama 7000005, Japan
关键词
D O I
10.1246/cl.2004.1298
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The arylene-ethynylene arrays involving pyridine were constructed successfully by taking advantage of double elimination reaction of beta-substituted sulfones (sulfoximines) which are easily accessible from arylmethyl sulfones (sulfoximines) and aromatic aldehydes. This protocol was utilized for synthesis of an enantiopure arylene-ethynylene framework bearing a binaphthyl stereogenic core.
引用
收藏
页码:1298 / 1299
页数:2
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