[Pd(Fmes)I{NMe2(CH2-o-C6H4-I)-N,I}], a palladium(II) complex with I- and organic iodide as trans ligands

被引：16

作者：

Bartolomé, C ^{[1
]}

Espinet, P ^{[1
]}

Martín-Alvarez, JM ^{[1
]}

Villafañe, F ^{[1
]}

机构：

[1] Univ Valladolid, Fac Ciencias, Dept Quim Inorgan, E-47005 Valladolid, Spain

来源：

INORGANICA CHIMICA ACTA | 2003年 / 347卷

关键词：

palladium complexes; iodocarbon; iodide; six-membered metalacycles;

D O I：

10.1016/S0020-1693(02)01435-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The treatment of [Pd(dmba)(Fmes)(OH2)] with I-2 leads to the formation of [Pd(Fmes)I {NMe2(CH2-o-C6H4-I)-N,I}]. The X-ray structure shows that a new halocarbon ligand, (2-iodobenzyl)dimethylamine has been formed and is acting as N-I chelate. The two different types of iodine, one iodide ligand and one organic iodide coordinated to Pd, are mutually trans and display essentially identical Pd-I distances. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：49 / 52

页数：4

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