Cation-triggered 'switching on' of the red/near infra-red (NIR) fluorescence of rigid fluorophore-spacer-receptor ionophores

被引:134
作者
Rurack, K
Resch-Genger, U
Bricks, JL
Spieles, M
机构
[1] Fed Inst Mat Res & Testing BAM, Dept 1 3902, D-12489 Berlin, Germany
[2] Natl Acad Sci Ukraine, Inst Organ Chem, UA-253660 Kiev 94, Ukraine
关键词
D O I
10.1039/b006430k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Fluorophore-spacer-receptor ionophores 1 and 2 show a strong cation-induced enhancement of the fluorescence at lambda > 650 nm in the presence of Hg-II and Ag-I (1) or Pb-II, alkaline-earth and alkali metal ions (2).
引用
收藏
页码:2103 / 2104
页数:2
相关论文
共 35 条
[1]   CHELATION-ENHANCED FLUORESCENCE OF ANTHRYLAZAMACROCYCLE CONJUGATE PROBES IN AQUEOUS-SOLUTION [J].
AKKAYA, EU ;
HUSTON, ME ;
CZARNIK, AW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (09) :3590-3593
[2]   Anion selective recognition and optical/electrochemical sensing by novel transition-metal receptor systems [J].
Beer, PD .
CHEMICAL COMMUNICATIONS, 1996, (06) :689-696
[3]  
BISSELL RA, 1993, TOP CURR CHEM, V168, P223
[4]   ION-RESPONSIVE FLUORESCENT COMPOUNDS .4. EFFECT OF CATION BINDING ON THE PHOTOPHYSICAL PROPERTIES OF A COUMARIN LINKED TO MONOAZA-CROWN AND DIAZA-CROWN ETHERS [J].
BOURSON, J ;
POUGET, J ;
VALEUR, B .
JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (17) :4552-4557
[5]   OFF-ON FLUORESCENT SENSORS FOR PHYSIOLOGICAL LEVELS OF MAGNESIUM-IONS BASED, ON PHOTOINDUCED ELECTRON-TRANSFER (PET), WHICH ALSO BEHAVE AS PHOTOIONIC OR LOGIC GATES [J].
DE SILVA, AP ;
GUNARATNE, HQN ;
MAGUIRE, GEM .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (10) :1213-1214
[6]  
de Silva AP, 1999, CHEM COMMUN, P163
[7]   Fluorescent signalling of the brain neurotransmitter gamma-aminobutyric acid and related amino acid zwitterions [J].
de Silva, AP ;
Gunaratne, HQN ;
McVeigh, C ;
Maguire, GEM ;
Maxwell, PRS ;
OHanlon, E .
CHEMICAL COMMUNICATIONS, 1996, (18) :2191-2192
[8]   Fluorescent switches with high selectivity towards sodium ions: Correlation of ion-induced conformation switching with fluorescence function [J].
de Silva, AP ;
Gunaratne, HQN ;
Gunnlaugsson, T ;
Nieuwenhuizen, M .
CHEMICAL COMMUNICATIONS, 1996, (16) :1967-1968
[9]   Signaling recognition events with fluorescent sensors and switches [J].
de Silva, AP ;
Gunaratne, HQN ;
Gunnlaugsson, T ;
Huxley, AJM ;
McCoy, CP ;
Rademacher, JT ;
Rice, TE .
CHEMICAL REVIEWS, 1997, 97 (05) :1515-1566
[10]   FLUORESCENT SIGNALING CROWN ETHERS - SWITCHING ON OF FLUORESCENCE BY ALKALI-METAL ION RECOGNITION AND BINDING INSITU [J].
DE SILVA, AP ;
DESILVA, SA .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (23) :1709-1710