Revisiting Perkin's dye(s): the spectroscopy and photophysics of two new mauveine compounds (B2 and C)

被引：52

作者：

de Melo, J. Seixas ^{[1
]}

Takato, S.

Sousa, M.

Melo, M. J.

Parola, A. J.

机构：

[1] Univ Coimbra, Dept Chem, P-3004535 Coimbra, Portugal

[2] Univ Nova Lisboa, Fac Ciencias & Tecnol, Dept Conservacao & Restauro, P-1200 Lisbon, Portugal

[3] Univ Nova Lisboa, REQUIMTE, Dept Quim, Fac Ciencias & Tecnol, P-2829516 Caparica, Portugal

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 25期

关键词：

D O I：

10.1039/b618926a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two new components have been identified in an early sample prepared according to the original recipe of Perkin, and perhaps even by Perkin himself around 1860 - a new isomer of Perkin's mauveine B (designated as mauveine B2) together with a new mauveine compound (mauveine C) - and these compounds were synthesized again using starting materials chosen to reproduce Perkin's original synthesis and isolated by HPLC-DAD, identified by H-1 NMR, MS and their spectroscopic (UV/Vis and emission) and photophysical behaviour investigated.

引用

页码：2624 / 2626

页数：3

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