Influence of residual carbon on the photocatalytic activity of TiO2/samples for phenol oxidation

被引:45
作者
Colón, G [1 ]
Hidalgo, MC [1 ]
Macías, M [1 ]
Navío, JA [1 ]
Doña, JM [1 ]
机构
[1] Univ Seville, CSIC, Ctr Mixto, Inst Ciencia Mat Sevilla, Seville 41092, Spain
关键词
TiO2; active carbon; residual carbon; sol-gel; phenol photo-oxidation; photocatalysis;
D O I
10.1016/S0926-3373(02)00300-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
TiO2 nanoparticles have been prepared by a novel alkoxide sol-gel precipitation. The presence of active carbon in different percentages could act as an interesting template. Upon calcination, carbon is eliminated leaving surface features significantly different from TiO2 prepared in the absence of carbon. Influence of calcination temperature and times will be studied. Detailed surface and structural characterisation of samples have been carried out. The correlations between residual carbon percentage after thermal treatment and photoactivity during phenol oxidation are reported. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:163 / 173
页数:11
相关论文
共 17 条
  • [1] ANPO M, 1988, J PHYS CHEM-US, V92, P92
  • [2] MOLECULAR FRACTAL SURFACES
    AVNIR, D
    FARIN, D
    PFEIFER, P
    [J]. NATURE, 1984, 308 (5956) : 261 - 263
  • [3] AVNIR D, 1990, OPTIMAL STRUCTURES H
  • [4] A novel preparation of high surface area TiO2 nanoparticles from alkoxide precursor and using active carbon as additive
    Colón, G
    Hidalgo, MC
    Navío, JA
    [J]. CATALYSIS TODAY, 2002, 76 (2-4) : 91 - 101
  • [5] Photocatalytic deactivation of commercial TiO2 samples during simultaneous photoreduction of Cr(VI) and photooxidation of salicylic acid
    Colón, G
    Hidalgo, MC
    Navío, JA
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2001, 138 (01) : 79 - 85
  • [6] SIZE EFFECTS IN PHOTOPROCESSES ON DISPERSED CATALYSTS
    FARIN, D
    KIWI, J
    AVNIR, D
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (15) : 5851 - 5854
  • [7] FARIN D, 1991, J PHYS CHEM-US, V95, P6100
  • [8] Preparation of fine TiO2 powders via spray hydrolysis of titanium tetraisopropoxide
    Gablenz, S
    Voltzke, D
    Abicht, HP
    Neumann-Zdralek, J
    [J]. JOURNAL OF MATERIALS SCIENCE LETTERS, 1998, 17 (07) : 537 - 539
  • [9] XRD, Raman and FT-IR spectroscopic observations of nanosized TiO2 synthesized by the sol-gel method based on an esterification reaction
    Ivanda, M
    Music, S
    Popovic, S
    Gotic, M
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 1999, 481 : 645 - 649
  • [10] Effect of the type of activated carbons on the photocatalytic degradation of aqueous organic pollutants by UV-irradiated titania
    Matos, J
    Laine, J
    Herrmann, JM
    [J]. JOURNAL OF CATALYSIS, 2001, 200 (01) : 10 - 20