Exciton-bath coupling and inhomogeneous broadening in the optical spectroscopy of semiconductor quantum dots

被引：80

作者：

Salvador, MR ^{[1
]}

Hines, MA ^{[1
]}

Scholes, GD ^{[1
]}

机构：

[1] Univ Toronto, Lash Miller Chem Labs, Toronto, ON M5S 3H6, Canada

来源：

JOURNAL OF CHEMICAL PHYSICS | 2003年 / 118卷 / 20期

关键词：

D O I：

10.1063/1.1568733

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The homogeneous line shape and inhomogeneous broadening of colloidal quantum dots are measured at ambient temperatures and in solution. Three-pulse echo peak shift (3PEPS) measurements of nanocrystalline CdSe semiconductor quantum dots in toluene solvent at 298 K are reported. Modeling of the 3PEPS data using a detailed model designed to account for the optical properties of semiconductor quantum dots, suggests that Debye-type relaxations attributed to reorientation of the trioctylphosphine and trioctyl phosphine oxide capping ligands are significant. It is shown that 3PEPS spectroscopy can quantify precisely the inhomogeneous broadening of the optical spectrum, brought about mainly by the distribution of nanocrystal sizes. (C) 2003 American Institute of Physics.

引用

页码：9380 / 9388

页数：9

共 68 条

[1] ELECTRON-VIBRATION COUPLING IN SEMICONDUCTOR CLUSTERS STUDIED BY RESONANCE RAMAN-SPECTROSCOPY [J].

ALIVISATOS, AP ;

HARRIS, TD ;

CARROLL, PJ ;

STEIGERWALD, ML ;

BRUS, LE .

JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (07) :3463-3468

[2] ELECTRONIC STATES OF SEMICONDUCTOR CLUSTERS - HOMOGENEOUS AND INHOMOGENEOUS BROADENING OF THE OPTICAL-SPECTRUM [J].

ALIVISATOS, AP ;

HARRIS, AL ;

LEVINOS, NJ ;

STEIGERWALD, ML ;

BRUS, LE .

JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (07) :4001-4011

[3] Perspectives on the physical chemistry of semiconductor nanocrystals [J].

Alivisatos, AP .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (31) :13226-13239

[4]

ANG S, UNPUB

[5]

BANYAI L, 1993, SEMICONDUCTOR QUANTU

[6] Photoluminescence wandering in single CdSe nanocrystals [J].

Blanton, SA ;

Hines, MA ;

GuyotSionnest, P .

APPLIED PHYSICS LETTERS, 1996, 69 (25) :3905-3907

[7] RELAXATION EFFECTS IN NUCLEAR MAGNETIC RESONANCE ABSORPTION [J].

BLOEMBERGEN, N ;

PURCELL, EM ;

POUND, RV .

PHYSICAL REVIEW, 1948, 73 (07) :679-712

[8] IMPULSIVE PUMP-PROBE AND PHOTON-ECHO SPECTROSCOPIES OF DYE MOLECULES IN CONDENSED PHASES [J].

BOSMA, WB ;

YAN, YJ ;

MUKAMEL, S .

PHYSICAL REVIEW A, 1990, 42 (11) :6920-6923

[9] ELECTRON ELECTRON AND ELECTRON-HOLE INTERACTIONS IN SMALL SEMICONDUCTOR CRYSTALLITES - THE SIZE DEPENDENCE OF THE LOWEST EXCITED ELECTRONIC STATE [J].

BRUS, LE .

JOURNAL OF CHEMICAL PHYSICS, 1984, 80 (09) :4403-4409

[10]

Chemla DS, 1999, SEMICONDUCT SEMIMET, V58, P175

← 1 2 3 4 5 6 7 →