Iron(II) triflate salts as convenient substitutes for perchlorate salts:: Crystal structures of [Fe(H2O)6](CF3SO3)2 and Fe(MeCN)4(CF3SO3)2

被引：170

作者：

Hagen, KS ^{[1
]}

机构：

[1] Emory Univ, Dept Chem, Atlanta, GA 30322 USA

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 25期

关键词：

D O I：

10.1021/ic000444w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The most convenient source of anhydrous iron(II) triflate is the acetonitrile solvate isolated from the reaction of finely divided iron metal with triflic acid in acetonitrile. The crystalline Fe(MeCN)4(OTf)2 readily loses two MeCN molecules under vacuum to afford Fe(OTf)2·2MeCN, which is stable to air oxidation but absorbs water. Crystals of the hexahydrate containing a hydrogen-bonded, layered structure are obtained from water.

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页码：5867 / 5869

页数：3

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