Fermi resonance distortion of the Ru-CO stretching mode of CO adsorbed on Ru(001)

被引：34

作者：

Jakob, P ^{[1
]}

机构：

[1] Tech Univ Munchen Weihenstephan, Phys Dept E20, D-85747 Garching, Germany

来源：

JOURNAL OF CHEMICAL PHYSICS | 1998年 / 108卷 / 12期

关键词：

D O I：

10.1063/1.475910

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A Fermi resonance of the Ru-CO stretching mode and the combination band of the hindered rotation+hindered translation mode of adsorbed CO on Ru(001) has been detected using infrared absorption spectroscopy. The Fermi resonance has been unambiguously identified through isotopic substitution experiments at various CO coverages. Clear evidence for a delocalized nature of the Fermi resonance is found. (C) 1998 American Institute of Physics.

引用

页码：5035 / 5043

页数：9

共 18 条

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