Efficient carbonate synthesis under mild conditions through cycloaddition of carbon dioxide to oxiranes using a Zn(salphen) catalyst

被引：261

作者：

Decortes, Antonello ^{[1
]}

Martinez Belmonte, Marta ^{[1
]}

Benet-Buchholz, Jordi ^{[1
]}

Kleij, Arjan W. ^{[1
,2
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

[2] Catalan Inst Res & Adv Studies ICREA, Barcelona 08010, Spain

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 25期

关键词：

CYCLIC CARBONATES; SALEN COMPLEXES; ALTERNATING COPOLYMERIZATION; CYCLOHEXENE OXIDE; EPOXIDES; CO2; POLYCARBONATES; PRESSURE; FIXATION; ZN;

D O I：

10.1039/c000493f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zn(salphen) complexes are reported as effective, cheap, robust and relatively green catalysts for the cycloaddition of carbon dioxide to terminal epoxides to afford cyclic carbonates in good yields.

引用

页码：4580 / 4582

页数：3

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