Synthesis and magnetic properties of wheel-shaped [Mn12] and [Fe6] complexes

被引：70

作者：

Rumberger, EM ^{[1
]}

Zakharov, LN ^{[1
]}

Rheingold, AL ^{[1
]}

Hendrickson, DN ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

INORGANIC CHEMISTRY | 2004年 / 43卷 / 21期

关键词：

D O I：

10.1021/ic0488886

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of the ligands N-methyldiethanol amine and N-ethyldiethanol amine (abbreviated H(2)mdea and H(2)edea, respectively) with [Mn12O12(O2CCH3)(16)(H2O)(4)] yield novel dodecanuclear wheel-shaped products. The capability of the ligands H2mdea and H2edea to support wheel structures in metals other than Mn is demonstrated with the crystal structure of a new hexanuclear ferric wheel.

引用

页码：6531 / 6533

页数：3

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