A study of oxyfluorination of multi-walled carbon nanotubes on mechanical interfacial properties of epoxy matrix nanocomposites

被引:65
作者
Park, SJ
Jeong, HJ
Nah, C
机构
[1] Korea Res Inst Chem Technol, Adv Mat Div, Taejon 305600, South Korea
[2] Chonbuk Natl Univ, Dept Polymer Sci & Engn, Chonju 561756, South Korea
来源
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING | 2004年 / 385卷 / 1-2期
关键词
oxyfluorination; multi-walled carbon nanotubes; surface properties; mechanical properties; mechanical interfacial properties;
D O I
10.1016/j.msea.2004.03.041
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Multi-walled carbon nanotubes (MWNTs) were oxyfluorinated at several different temperatures. The changes of surface properties of oxyfluorinated MWNTs were investigated using FIF-IR, EDS and XRD. The treated MWNTs were embedded in the epoxy resin and the fracture behavior of the resulting composites was determined by impact and fracture toughness tests. From the surface analysis, it was found that surface fluorine and oxygen contents increased with increasing oxyfluorination temperature and showed a maximum value at 100 degreesC. This led to an increase of surface polarity of the MWNTs, resulting in increasing K-IC and impact strength of the composites, due to the improvement of interfacial adhesion force between the MWNTs and the epoxy matrix. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:13 / 16
页数:4
相关论文
共 20 条
[1]  
Ajayan PM, 2000, ADV MATER, V12, P750, DOI 10.1002/(SICI)1521-4095(200005)12:10<750::AID-ADMA750>3.0.CO
[2]  
2-6
[3]   A multi-scale approach for the response of a 3D carbon/carbon composite under shock loading [J].
Allix, O ;
Dommanget, M ;
Gratton, M ;
Héreil, PL .
COMPOSITES SCIENCE AND TECHNOLOGY, 2001, 61 (03) :409-415
[4]   EFFECT OF PLASMA POLYMERIZATION ON CARBON-FIBERS USED FOR FIBER/EPOXY COMPOSITES [J].
DILSIZ, N ;
EBERT, E ;
WEISWEILER, W ;
AKOVALI, G .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1995, 170 (01) :241-248
[5]  
Donnet J.B., 1990, CARBON FIBERS
[6]   Electrodeposition of TiO2 photocatalyst into nano-pores of hard alumite [J].
Ishikawa, Y ;
Matsumoto, Y .
ELECTROCHIMICA ACTA, 2001, 46 (18) :2819-2824
[7]   Single-walled carbon nanotube-polymer composites: electrical, optical and structural investigation [J].
Kymakis, E ;
Alexandou, I ;
Amaratunga, GAJ .
SYNTHETIC METALS, 2002, 127 (1-3) :59-62
[8]  
NAKAJIMA T, 1995, FLUORIN CARBON FLUOR
[9]   Electrical properties of single wall carbon nanotube reinforced polyimide composites [J].
Ounaies, Z ;
Park, C ;
Wise, KE ;
Siochi, EJ ;
Harrison, JS .
COMPOSITES SCIENCE AND TECHNOLOGY, 2003, 63 (11) :1637-1646
[10]   Effect of acidic anode treatment on carbon fibers for increasing fiber-matrix adhesion and its relationship to interlaminar shear strength of composites [J].
Park, SJ ;
Kim, MH .
JOURNAL OF MATERIALS SCIENCE, 2000, 35 (08) :1901-1905