Molecules with a genuine Si-Si triple bond and a stable derivative of [SiH]+

被引：30

作者：

Weidenbruch, M ^{[1
]}

机构：

[1] Univ Oldenburg, Inst Reine & Angew Chem, D-26111 Oldenburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 04期

关键词：

cations; half-sandwich compounds; multiple bonds; silicon;

D O I：

10.1002/anie.200462273

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bye bye multiple-bond rule: Recent successes in silicon chemistry are the silicon-containing compounds 1, which has a Si-Si triple bond, and the [(Me 5C5)Si]+ ion 2, which is a stable derivative of the [HSi]+ ion. Both species are also notable from a bond-theory point of view and can be regarded as valuable starting materials for synthetic organosilicon chemistry.

引用

页码：514 / 516

页数：3

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