Rigid and flexible: A highly porous metal-organic framework with unusual guest-dependent dynamic behavior

被引：1062

作者：

Dybtsev, DN

Chun, H

Kim, K

机构：

[1] Pohang Univ Sci & Technol, Natl Creat Res Initiat Ctr Smart Supramol, Pohang 790784, South Korea

[2] Pohang Univ Sci & Technol, Dept Chem, Div Mol & Life Sci, Pohang 790784, South Korea

[3] Russian Acad Sci, Inst Inorgan Chem, Novosibirsk 630090, Russia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 38期

关键词：

carboxylate ligands; coordination polymers; gas sorption; host-guest systems;

D O I：

10.1002/anie.200460712

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A large H2 sorption capacity and high surface area are properties of the depicted metal-organic porous material, which is easily synthesized on a large scale from readily available chemicals. The rigid framework of [Zn2(1,4-bdc)2(dabco)] (1,4-H2bdc = 1,4-benzenedicarboxylic acid; dabco = diazabicyclo[2.2.2]octane) is also flexible enough to exhibit unusual guest-dependent dynamic behavior, as shown (DMF = N,N-dimethylformamide).

引用

页码：5033 / 5036

页数：4

共 51 条

[1]

[Anonymous], 2004, Angew. Chem, V116, P2388, DOI DOI 10.1016/j.jechem.2020.01.001

[2]

Barthelet K, 2002, ANGEW CHEM INT EDIT, V41, P281, DOI 10.1002/1521-3773(20020118)41:2<281::AID-ANIE281>3.0.CO

[3]

2-Y

[4]

Barthelet K., 2002, ANGEW CHEM, V114, P291, DOI DOI 10.1002/1521-3757(20020118)114:2<291:AID-ANGE291>3.0.CO

[5]

2-I

[6]

Biradha K, 2002, ANGEW CHEM INT EDIT, V41, P3392, DOI 10.1002/1521-3773(20020916)41:18<3392::AID-ANIE3392>3.0.CO

[7]

2-V

[8]

Biradha K., 2002, ANGEW CHEM, V114, P3542

[9] Permanent microporosity and enantioselective sorption in a chiral open framework [J].

Bradshaw, D ;

Prior, TJ ;

Cussen, EJ ;

Claridge, JB ;

Rosseinsky, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (19) :6106-6114

[10] A route to high surface area, porosity and inclusion of large molecules in crystals [J].

Chae, HK ;

Siberio-Pérez, DY ;

Kim, J ;

Go, Y ;

Eddaoudi, M ;

Matzger, AJ ;

O'Keeffe, M ;

Yaghi, OM .

NATURE, 2004, 427 (6974) :523-527

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