The strongest isolable acid

被引：136

作者：

Juhasz, M

Hoffmann, S

Stoyanov, E

Kim, KC

Reed, CA ^{[1
]}

机构：

[1] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

[2] Boreskov Inst Catalysis, Novosibirsk 630090, Russia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 40期

关键词：

acids; basicity suppression; Bronsted acids; carboranes; IR spectroscopy;

D O I：

10.1002/anie.200460005

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Measure for measure: Several measures indicate that carborane acids of the type H(CHB11R5X6) (see scheme, green R, red X, gray H, pink B) for R = H, Cl and X = Cl, Br, I are the strongest pure Bronsted acids. Based on NMR and IR spectroscopy, H(CHB11Cl11) can lay claim to be the strongest isolable acid presently known.

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页码：5352 / 5355

页数：4

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