A novel heterometallic μ4-oxo-bridged complex based on an octahedral Cd2Cu4 skeleton via the reaction of elemental copper, cadmium acetate and amino alcohol

被引：10

作者：

Vinogradova, EA

Kokozay, VN

Vassilyeva, OY

Skelton, BW

机构：

[1] Natl Taras Shevchenko Univ, Dept Inorgan Chem, UA-01033 Kiev, Ukraine

[2] Univ Western Australia, Dept Chem, Crawley, WA 6009, Australia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 01期

关键词：

heterometallic complex; zero-valent copper; 2-dimethylaminoethanol; mu(4)-bridging oxygen; crystal structure;

D O I：

10.1016/S1387-7003(02)00688-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of copper powder in dmso with cadmium acetate hydrate and 2-dimethylaminoethanol (HL), in open air, afforded [Cd2Cu4(mu(4)-O)(O2CMe)(6)L-4] . 2H(2)O with a metal skeleton that approximates an octahedron. The copper atoms are tetrahedrally arranged about the oxygen atom in a considerably distorted fashion. The amino alkoxo and acetate ligands display a variety of bonding modes in the complex. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：82 / 85

页数：4

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