Colloidal cluster phases, gelation and nuclear matter

被引:66
作者
Groenewold, J
Kegel, WK
机构
[1] Delft Univ Technol, Fac Sci Appl, NL-2628 BL Delft, Netherlands
[2] Univ Utrecht, Debye Res Inst, Vant Hoff Lab Phys & Colloid Chem, NL-3584 CH Utrecht, Netherlands
关键词
D O I
10.1088/0953-8984/16/42/006
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The combination of short-range attractions and long-range repulsions can lead to interesting clustering phenomena. In particular there are strong indications that the colloidal cluster phase is in fact a manifestation of such a competition. Here we compute the stability boundary of the cluster phase by invoking counter-ion condensation. It is found that a condensation catastrophe leading to an infinite cluster sets in if the level of charge on the colloid is too low. The same ingredients leading to the cluster phase are found in nuclear physics: strong short-range attractions due to nuclear force and weak long-range Coulomb repulsions. We will show explicitly here the equivalence of a semi-empirical mass formula for the binding energy of the nucleus and the free energy of a cluster in a colloidal cluster phase. This identification enables an exploitation of theoretical results from nuclear physics to the colloidal domain and, perhaps, the construction of a colloidal system mimicking various aspects of nuclear matter.
引用
收藏
页码:S4877 / S4886
页数:10
相关论文
共 25 条
[1]  
[Anonymous], 1992, INTERMOLECULAR SURFA
[2]   ON INTERACTION BETWEEN 2 BODIES IMMERSED IN A SOLUTION OF MACROMOLECULES [J].
ASAKURA, S ;
OOSAWA, F .
JOURNAL OF CHEMICAL PHYSICS, 1954, 22 (07) :1255-1256
[3]   NEUTRON STAR MATTER [J].
BAYM, G ;
BETHE, HA ;
PETHICK, CJ .
NUCLEAR PHYSICS A, 1971, A175 (02) :225-&
[4]  
BURCHAM WE, 1971, NUCL PHYS INTRO
[5]   NEW MONTE-CARLO METHOD TO COMPUTE THE FREE-ENERGY OF ARBITRARY SOLIDS - APPLICATION TO THE FCC AND HCP PHASES OF HARD-SPHERES [J].
FRENKEL, D ;
LADD, AJC .
JOURNAL OF CHEMICAL PHYSICS, 1984, 81 (07) :3188-3193
[6]   Anomalously large equilibrium clusters of colloids [J].
Groenewold, J ;
Kegel, WK .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (47) :11702-11709
[7]  
HAENSEL P, 2001, PHYS NEUTRON STAR IN
[8]   THEORY OF MICROPHASE SEPARATION IN BLOCK CO-POLYMERS [J].
LEIBLER, L .
MACROMOLECULES, 1980, 13 (06) :1602-1617
[9]  
MOSKOWSKI SA, 1957, HDB PHYS, V39
[10]   Multiple glassy states in a simple model system [J].
Pham, KN ;
Puertas, AM ;
Bergenholtz, J ;
Egelhaaf, SU ;
Moussaïd, A ;
Pusey, PN ;
Schofield, AB ;
Cates, ME ;
Fuchs, M ;
Poon, WCK .
SCIENCE, 2002, 296 (5565) :104-106