Organometallic halides:: Structure and magnetism of tris[(η-pentamethylcyclopentadienyl)dichlorovanadium], [(η-C5Me5)V(μ-Cl)2]3

被引:6
作者
Abernethy, CD
Bottomley, F
Decken, A
Summers, DA
Thompson, RC
机构
[1] Univ New Brunswick, Dept Chem, Fredericton, NB E3B 6E2, Canada
[2] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada
关键词
D O I
10.1021/om970903+
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
There are layers of [(eta-C5Me5)V(mu-Cl)(2)](3) parallel to the a,b plane in both crystalline forms of this antiferromagnetic cluster. In form I, each layer is rotated 60 degrees with respect to neighboring layers, whereas in form II it is rotated by 30 degrees.
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收藏
页码:1248 / 1250
页数:3
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