A general synthesis of vinylic silyl hydrides using nickel catalysis. Applications to the syntheses of silylene-tethered conjugated polymers

被引：24

作者：

Chen, RM ^{[1
]}

Luh, TY ^{[1
]}

机构：

[1] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan

来源：

TETRAHEDRON | 1998年 / 54卷 / 07期

关键词：

D O I：

10.1016/S0040-4020(97)10218-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of benzylic or allylic dithioacetals with Me-2((PrO)-Pr-i)SiCH2MgCl in the presence of NiCl2(PPh3)(2) catalyst yielded the corresponding i-propoxy(vinyl)silanes which are reduced with LIAlH4, to afford vinylic silyl hydrides. These hydrides serve as the precursors for the syntheses of silylene-tethered sigma,pi-conjugated copolymers. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：1197 / 1206

页数：10

共 46 条

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