A biopolymer composite that catalyzes the reduction of oxygen to water

被引：38

作者：

Fei, Jiangfeng

Song, Hyun-Kon

Palmore, G. Tayhas R. ^{[1
]}

机构：

[1] Brown Univ, Div Engn, Providence, RI 02912 USA

[2] Brown Univ, Div Biol & Med, Providence, RI 02912 USA

来源：

CHEMISTRY OF MATERIALS | 2007年 / 19卷 / 07期

关键词：

D O I：

10.1021/cm0608490

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A biopolymer composite consisting of polypyrrole, ABTS, and laccase (PAL) was electrodeposited onto the surface of an electrode and was shown to catalyze the reduction of dioxygen to water under acidic conditions. The catalytic activity of this biopolymer composite is highest at pH 4, decreasing with increasing pH. The activity of laccase immobilized within this polymer composite was found to be higher than laccase dissolved in solution when methanol was present or at elevated temperatures.

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页码：1565 / 1570

页数：6

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