Hydrocracking of n-heptane on a sulfided NiMo-Y zeolite catalyst: Effect of the sulfidation method

The activity and the selectivity of a bifunctional NiMo sulfides-Y zeolite catalyst for n-heptane hydrocracking depend very much on the sulfidation agent, namely hydrogen sulfide, or dimethyldisulfide in solution in n-heptane or n-decane. The presence of a hydrocarbon during the sulfidation lowers the acid activity of the catalyst because of coking of the zeolite acid sites, and also decreases the hydrogenating activity, due to a poorer sulfidation of the catalyst.